TITANIUM(IV) FULVALENE COMPLEXES - PREPARATION AND STRUCTURE OF [CPTIPH2]2(C10H8)

Authors
THEWALT U WOHRLE T
Citation
U. Thewalt et T. Wohrle, TITANIUM(IV) FULVALENE COMPLEXES - PREPARATION AND STRUCTURE OF [CPTIPH2]2(C10H8), Zeitschrift fur Naturforschung. B, A journal of chemical sciences, 48(5), 1993, pp. 603-607
Citations number
8
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur Naturforschung. B, A journal of chemical sciences → ACNP
ISSN journal
09320776
Volume
48
Issue
5
Year of publication
1993
Pages
603 - 607
Database
ISI
SICI code
0932-0776(1993)48:5<603:TFC-PA>2.0.ZU;2-#
Abstract
The green insoluble Ti(IV) compound which is obtained by treating tita nocene with HCl reacts with PhLi to yield the fulvalene-bridged compou nd [CpTiPh2]2(C10H8) 3(Ph). An X-ray structure analysis of 3(Ph) shows , that the Ti atoms are in a trans arrangement with respect to the ful valene group. Crystal data for 3(Ph) are as follows: C44H38Ti2, orthor hombic. space group P2(1)2(1)2(1), with a = 11,385(2), b = 14,510(2), c = 19,489(4) angstrom, Z = 4. The crystals exhibit enantiomorphism.