CHARACTERIZATION AND PROPERTIES OF CH3C(CH2PPH2)3MOCL3

Authors
WALTER O HUTTNER G ZSOLNAI L
Citation
O. Walter et al., CHARACTERIZATION AND PROPERTIES OF CH3C(CH2PPH2)3MOCL3, Zeitschrift fur Naturforschung. B, A journal of chemical sciences, 48(5), 1993, pp. 636-640
Citations number
37
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur Naturforschung. B, A journal of chemical sciences → ACNP
ISSN journal
09320776
Volume
48
Issue
5
Year of publication
1993
Pages
636 - 640
Database
ISI
SICI code
0932-0776(1993)48:5<636:CAPOC>2.0.ZU;2-N
Abstract
Starting from MoCl5 via the intermediates (MeCN)2MoCl4 (1) and (THF)2M oCl4 (2) the tripod complex CH3C(CH2PPh2)3MoCl3 (4) has been synthesiz ed. The yellow cristalline compound 4 has been fully characterized by standard analytical techniques. X-ray-analysis proves the facial coord ination of the tripod ligand. To our knowledge 4 is the first Mo(III)- trihalide coordination compound containing three P-donor-ligands in a facial coordination.