FORMATION OF CYCLOPROPYL CARBINOLS THROUGH A HIGHLY DIASTEREOSELECTIVE HYDROZIRCONATION OF VINYLOXIRANE DERIVATIVES
Citation
S. Harada et al., FORMATION OF CYCLOPROPYL CARBINOLS THROUGH A HIGHLY DIASTEREOSELECTIVE HYDROZIRCONATION OF VINYLOXIRANE DERIVATIVES, Tetrahedron letters, 38(11), 1997, pp. 1957-1960
Categorie Soggetti
Chemistry Inorganic & Nuclear
SICI code
0040-4039(1997)38:11<1957:FOCCTA>2.0.ZU;2-I
Abstract
Cyclopropyl carbinol derivatives were efficiently prepared through a h
ighly diastereoselective hydrozirconation of vinyloxiranes and the int
ramolecular nucleophilic attack of the generated alkylzirconocene with
the inversion of the configuration at the reacting oxirane carbon. (C
) 1997 Elsevier Science Ltd.
