The paper presents results of experimental work carried out to study t
he role of surface active agents in the dewatering of fine clean coal.
The fundamental phenomena which determine their mode of action are ex
amined, and the mechanism of surfactant-enhanced dewatering is investi
gated in terms of the surface chemical phenomena and the physical proc
esses involved in the dewatering. The performance and possible mode of
action are compared between two surfactant dewatering aids. The resul
ts of dewatering experiments show that the presence of the sodium dode
cyl sulphate leads to a very significant reduction in the final residu
al cake moisture content, A direct and strong correlation exists betwe
en the point of zero charge, surface tension reduction In the coal sys
tem and residual moisture reduction in the filter cake. These improvem
ents are attributed to the changes in the wetting characteristics of t
he coal particles in the presence of effective dewatering aids.