SYNTHESIS AND CHARACTERIZATION OF HETEROBINUCLEAR (LA-ZN, PR-ZN, ND-ZN, SM-ZN, EU-ZN, GD-ZN, TB-ZN, DY-ZN) AZINE-BRIDGED COMPLEXES

Authors
SINGH B SRIVASTAV AK SINGH PK
Citation
B. Singh et al., SYNTHESIS AND CHARACTERIZATION OF HETEROBINUCLEAR (LA-ZN, PR-ZN, ND-ZN, SM-ZN, EU-ZN, GD-ZN, TB-ZN, DY-ZN) AZINE-BRIDGED COMPLEXES, Indian journal of chemistry. Sect. A: Inorganic, physical, theoretical & analytical, 36(1), 1997, pp. 72-76
Citations number
23
Categorie Soggetti
Chemistry
Journal title
Indian journal of chemistry. Sect. A: Inorganic, physical, theoretical & analytical → ACNP
ISSN journal
03764710
Volume
36
Issue
1
Year of publication
1997
Pages
72 - 76
Database
ISI
SICI code
0376-4710(1997)36:1<72:SACOH(>2.0.ZU;2-H
Abstract
Zinc(II) complex of 2-acetylpyridine salicyl aldazine (Haps) of the ty pe Zn(aps)(2)(H2O)(2) has been synthesised. The reaction of Zn(aps)(2) (H2O)(2) with latathanide chlorides, LnCl(3) (where Ln=La, Pr, Nd, Sm, Eu, Gd, Tb and Dy) yields azine-bridged heterobinuclear complexes of the formulae LnCl(3)Zn(aps)(2)(H2O)(2). These complexes have been char acterized by elemental analyses molecular weight, conductance (solid a nd solution) and magnetic susceptibility measurements, mass, IR and el ectronic spectral data. X-ray powder diffraction data indicate the tet ragonal unit lattice for Zn(aps)(2)(H2O)(2) and PrCl3Zn(aps)(2)(H2O)(2 ).