STRUCTURAL STUDIES OF COPPER(II) COMPLEXES WITH TRIPHENYLPHOSPHINE OXIDE

Authors
LOBANA TS GOSAIN A PAUL S
Citation
Ts. Lobana et al., STRUCTURAL STUDIES OF COPPER(II) COMPLEXES WITH TRIPHENYLPHOSPHINE OXIDE, Indian journal of chemistry. Sect. A: Inorganic, physical, theoretical & analytical, 36(1), 1997, pp. 82-83
Citations number
7
Categorie Soggetti
Chemistry
Journal title
Indian journal of chemistry. Sect. A: Inorganic, physical, theoretical & analytical → ACNP
ISSN journal
03764710
Volume
36
Issue
1
Year of publication
1997
Pages
82 - 83
Database
ISI
SICI code
0376-4710(1997)36:1<82:SSOCCW>2.0.ZU;2-1
Abstract
The solid-state reactions of copper(II) chloride dihydrate and dimeric copper(II) acetate dihydrate with triphenylphosphine oxide (Ph,PO), h ave been studied using infrared and X-band ESR spectroscopy. The solid mixtures are heated in air for 1 h in the temperature range 60-180 de grees C(+/- 2 degrees C) and each sample is cooled to room temperature (35 degrees C) before record ing their spectra. The data suggest the formation of CuCI2(OPPh(3))(OH2), CuCl2(OPPh(3))(2) and [Cu(OOCCH3)(2) (OPPh(3))](2) complexes.