HYDROGENATION KINETICS AND MECHANISM OF STILBENE, CINNAMALDEHYDE AND CINNAMIC ACID BY ANCHORED MONTMORILLONITEBIPYRIDINEPALLADIUM(II)ACETATE

Authors
SWAMY KV SADANAND DT RAMESH B SAIPRAKASH PK
Citation
Kv. Swamy et al., HYDROGENATION KINETICS AND MECHANISM OF STILBENE, CINNAMALDEHYDE AND CINNAMIC ACID BY ANCHORED MONTMORILLONITEBIPYRIDINEPALLADIUM(II)ACETATE, Indian journal of chemistry. Sect. A: Inorganic, physical, theoretical & analytical, 36(1), 1997, pp. 102-104
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Indian journal of chemistry. Sect. A: Inorganic, physical, theoretical & analytical → ACNP
ISSN journal
03764710
Volume
36
Issue
1
Year of publication
1997
Pages
102 - 104
Database
ISI
SICI code
0376-4710(1997)36:1<102:HKAMOS>2.0.ZU;2-4
Abstract
Hydrogenation of olefinic compounds catalysed by anchored catalysts is of current interest. A detailed kinetic study of the hydrogenation of some olefinic compounds over anchored montmorillonitebipyridine-palla dium(II) acetate catalyst which belongs to a new generation catalytic system is presented. The effects of substrate concentration, partial p ressure of hydrogen, catalyst concentration, solvent and temperature h ave been studied. Based on the results a mechanism is proposed, rate l aw derived and the corresponding thermodynamic parameters have been ev aluated. Product analysis is confirmed by H-NMR, LW and GLC.