Dm. Fleetwood et al., EFFECTS OF OXIDE TRAPS, INTERFACE TRAPS, AND BORDER TRAPS ON METAL-OXIDE-SEMICONDUCTOR DEVICES, Journal of applied physics, 73(10), 1993, pp. 5058-5074
We have identified several features of the 1/f noise and radiation res
ponse of metal-oxide-semiconductor (MOS) devices that are difficult to
explain with standard defect models. To address this issue, and in re
sponse to ambiguities in the literature, we have developed a revised n
omenclature for defects in MOS devices that clearly distinguishes the
language used to describe the physical location of defects from that u
sed to describe their electrical response. In this nomenclature, ''oxi
de traps'' are simply defects in the SiO2 layer of the MOS structure,
and ''interface traps'' are defects at the Si/SiO2 interface. Nothing
is presumed about how either type of defect communicates with the unde
rlying Si. Electrically, ''fixed states'' are defined as trap levels t
hat do not communicate with the Si on the time scale of the measuremen
ts, but ''switching states'' can exchange charge with the Si. Fixed st
ates presumably are oxide traps in most types of measurements, but swi
tching states can either be interface traps or near-interfacial oxide
traps that can communicate with the Si, i.e., ''border traps'' [D. M.
Fleetwood, IEEE Trans. Nucl. Sci. NS-39, 269 (1992)]. The effective de
nsity of border traps depends on the time scale and bias conditions of
the measurements. We show the revised nomenclature can provide focus
to discussions of the buildup and annealing of radiation-induced charg
e in non-radiation-hardened MOS transistors, and to changes in the 1/f
noise of MOS devices through irradiation and elevated-temperature ann
ealing. Border-trap densities of approximately 10(10)-10(11) cm-2 are
inferred from changes in switching-state density during postirradiatio
n annealing, and from a simple trapping model of the 1/f noise in MOS
devices. We also present a detailed study of charge buildup and anneal
ing in MOS capacitors with radiation-hardened oxides through steady-st
ate and switched-bias postirradiation annealing. Trapped-hole, trapped
-electron, and switching-state densities are inferred via thermally st
imulated current and capacitance-voltage measurements. A lower bound o
f approximately 3 X 10(11) cm-2 is estimated for the effective density
of border traps that contribute to the electrical response of the irr
adiated devices. This is roughly 20% of the observed switching-state d
ensity for these devices and irradiation conditions. To our knowledge,
this represents the first quantitative separation of measured switchi
ng-state densities into border-trap and interface-trap components. Pos
sible physical models of border traps are discussed. E' centers in SiO
2 (trivalent Si centers associated with oxygen vacancies) may serve as
border traps in many irradiated MOS devices.