Pt. Landsberg et Sg. Canagaratna, AVERAGE GIBBS ENERGY PER LATTICE DEFECT - A THERMODYNAMIC DERIVATION, Physical review. B, Condensed matter, 55(9), 1997, pp. 5531-5533
The statistical thermodynamics of defects is discussed from the point
of view of the thermodynamics of ideal solutions. This is used to deri
ve equations for the average Gibbs free energy per defect and a compar
ison is made with a recent statistical mechanical derivation.