The exchange of various trace species and energy at the earth's surfac
e plays an important role in climate, ecology, and human health and we
lfare. Surface exchange measurements can be difficult to obtain yet ar
e important to understand physical processes, assess environmental and
global change impacts, and develop robust parameterizations of atmosp
heric processes. The physics and turbulent structure of the atmospheri
c boundary layer are reviewed as they contribute to dry surface exchan
ge rates (fluxes). Micrometeorological, budget, and enclosure techniqu
es used to measure or estimate surface fluxes are described, along wit
h their respective advantages and limitations. Various measurement iss
ues (such as site characteristics, sampling considerations, sensor att
ributes, and flow distortion) impact on the ability to obtain represen
tative surface-based and airborne flux data.