We report the design, manufacture, and characterization of poled polym
er multilayer waveguides for frequency doubling. Phase matching is obt
ained by using modal dispersion between the zeroth-order fundamental l
ightwave and the first-order second-harmonic wave. By incorporating a
very thin high refractive index satellite layer, the phase-match condi
tion can be fulfilled with concomitant large overlap between the two w
aves, resulting in efficient doubling.