Significant progress has been made in the understanding of solidificat
ion conditions, microstructure evolution, and defect formation during
investment casting of NiAl single crystals. The high liquidus temperat
ures of NiAl alloys result in a larger dendrite arm spacing than is fo
und in superalloy Rene N5. Because of their higher thermal conductivit
ies, NiAl alloys have higher cooling rates and lower temperature gradi
ents during solidification than Rene N5. These differences give NiAl a
lloys a lower tendency to form freckles and a higher tendency to form
equiaxed grains. However, with the aid of process modeling, single cry
stals of various shapes of NiAl alloys have been produced.