A NEW MIXED ALKOXO ARYLOXO PALLADIUM COMPLEX WITH A BIDENTATE NITROGEN DONOR SYSTEM

Authors
KAPTEIJN GM GROVE DM VANKOTEN G SMEETS WJJ SPEK AL
Citation
Gm. Kapteijn et al., A NEW MIXED ALKOXO ARYLOXO PALLADIUM COMPLEX WITH A BIDENTATE NITROGEN DONOR SYSTEM, Inorganica Chimica Acta, 207(1), 1993, pp. 131-134
Citations number
14
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganica Chimica Acta → ACNP
ISSN journal
00201693
Volume
207
Issue
1
Year of publication
1993
Pages
131 - 134
Database
ISI
SICI code
0020-1693(1993)207:1<131:ANMAAP>2.0.ZU;2-4
Abstract
The reaction of [Pd(OPh)2(bpy)] with 1,1,1,3,3,3-hexafluoro-2-propanol affords a 'mixed' aryloxo alkoxo palladium complex, [Pd(OCH(CF3)2)(OP h)(HOPh)(bpy)] (4). A single crystal X-ray diffraction study of 4 show s the presence of an intermolecular O-H ... O hydrogen bond and an int ramolecular C-H ... O interaction, which could represent the initial s tage of a base-assisted beta-hydride elimination.