INFRARED-ABSORPTION IN HYDROGEN-BONDED COMPLEXES AND ABSORPTION OF ANEXCESS ELECTRON IN HYDROGEN-BONDED SOLVENTS

Authors
ABRAMCZYK H
Citation
H. Abramczyk, INFRARED-ABSORPTION IN HYDROGEN-BONDED COMPLEXES AND ABSORPTION OF ANEXCESS ELECTRON IN HYDROGEN-BONDED SOLVENTS, Vibrational spectroscopy, 5(1), 1993, pp. 109-117
Citations number
56
Categorie Soggetti
Spectroscopy,"Chemistry Analytical","Chemistry Physical
Journal title
Vibrational spectroscopy → ACNP
ISSN journal
09242031
Volume
5
Issue
1
Year of publication
1993
Pages
109 - 117
Database
ISI
SICI code
0924-2031(1993)5:1<109:IIHCAA>2.0.ZU;2-2
Abstract
A comparison was made between the theories of IR absorption in hydroge n-bonded complexes and near-IR and visible absorption of an excess ele ctron in hydrogen-bonded solvents. The near-IR and visible absorption spectra of excess electrons in water, alcohols, amines and alkanes wer e calculated in terms of electron-vibron coupling. The role of the hyd rogen bond on electron stabilization and solvation is discussed.