OCCURRENCE OF LIGAND COUPLING IN THE REACTION OF THE 2-THIENYL SULFOXIDES WITH ORGANOMETALLIC COMPOUNDS

Authors
OAE S INUBUSHI Y YOSHIHARA M
Citation
S. Oae et al., OCCURRENCE OF LIGAND COUPLING IN THE REACTION OF THE 2-THIENYL SULFOXIDES WITH ORGANOMETALLIC COMPOUNDS, Heteroatom chemistry, 4(2-3), 1993, pp. 185-188
Citations number
23
Categorie Soggetti
Chemistry
Journal title
Heteroatom chemistry → ACNP
ISSN journal
10427163
Volume
4
Issue
2-3
Year of publication
1993
Pages
185 - 188
Database
ISI
SICI code
1042-7163(1993)4:2-3<185:OOLCIT>2.0.ZU;2-M
Abstract
Treatment of 2-pyridyl 2-thienyl sulfoxide with 2-thienyllithium was f ound to give both 2-(2-pyridyl)thiophene 2 and 2,5-(di-2-pyridyl)thiop hene 3. The reaction between 2-thienyllithium and thionyl chloride was found to give 2,2'-bithienyl 8, a coupling product, which is also for med by the reaction between di-2-thienyl sulfoxide 7 and 2-thienyllith ium.