DIHALO DERIVATIVES OF 3-COORDINATE HYPERVALENT PHOSPHORUS-COMPOUNDS

Authors
ARDUENGO AJ BREKER J DAVIDSON F KLINE M
Citation
Aj. Arduengo et al., DIHALO DERIVATIVES OF 3-COORDINATE HYPERVALENT PHOSPHORUS-COMPOUNDS, Heteroatom chemistry, 4(2-3), 1993, pp. 213-221
Citations number
16
Categorie Soggetti
Chemistry
Journal title
Heteroatom chemistry → ACNP
ISSN journal
10427163
Volume
4
Issue
2-3
Year of publication
1993
Pages
213 - 221
Database
ISI
SICI code
1042-7163(1993)4:2-3<213:DDO3HP>2.0.ZU;2-E
Abstract
The preparation of yl-2,8-dioxa-1-phosphabicyclo[3.3.0]octa-3,6-diene (Dit-BuADPO . F2) from hexafluoropropylene oxide (HFPO) and ,8-dioxa-1 -phosphabicyclo-[3.3.0]octa-2,4,6-triene (DitBuADPO) is described. The solid state structure of DitBuADPO . F2 shows an unusual square pyram idal geometry. The structural and spectroscopic properties of DitBuADP O . F2 are compared with other oxidized derivatives of DitBuADPO that contain 5-coordinate phosphorus.