Vv. Demchenko et Aa. Urusovskaya, INFLUENCE OF IMPURITIES AND TESTING ATMOSPHERE ON HIGH-TEMPERATURE DEFORMATION OF CSI CRYSTALS, Crystal research and technology, 28(3), 1993, pp. 415-425
The influence of anion (bromine) and cation (cadmium and barium) impur
ities, as well as testing atmosphere (air, argon, vacuum) on high temp
erature deformation of CsI crystals is studied. This deformation in Cs
I has some peculiarities, which are the superplasticity signs and evid
encing about instability of a lattice state. All the impurities studie
d caused the hardening, their effect in superplasticity depends on its
solubility in the CsI lattice: the less the solubility, the stronger
the effect. With testing in vacuum and argon, when the formation of po
int defect clusters occurs, enhanced the superplasticity evidence comp
ared to that by testing in air, where clustering is prevented. These f
acts, as well as a quality resemblance of stress-strain curves of sing
le- and polycrystalline specimens give the basis for the conclusion, t
hat superplasticity is the manifestation of a plastic instability of t
he crystal, the instability centers may be precipitates and point defe
ct clusters.