PHOTOCHEMISTRY IN HG DOPED MATRICES - INFRARED-SPECTRA OF MERCURY HYDRIDES - HGH2, HGD2, HHGD, HGD

Authors
LEGAYSOMMAIRE N LEGAY F
Citation
N. Legaysommaire et F. Legay, PHOTOCHEMISTRY IN HG DOPED MATRICES - INFRARED-SPECTRA OF MERCURY HYDRIDES - HGH2, HGD2, HHGD, HGD, Chemical physics letters, 207(2-3), 1993, pp. 123-128
Citations number
14
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
Chemical physics letters → ACNP
ISSN journal
00092614
Volume
207
Issue
2-3
Year of publication
1993
Pages
123 - 128
Database
ISI
SICI code
0009-2614(1993)207:2-3<123:PIHDM->2.0.ZU;2-U
Abstract
Matrices of molecular hydrogen isotopes pure or diluted in argon and d oped with Hg have been irradiated with a KrF laser and studied by FTIR spectroscopy. Hg pumped to the P-3(1) state reacts with H-2, D2 and H D, giving new molecules: HgH2, HgD2 and HHgD. The three fundamental vi brational modes were identified and a linear symmetrical geometry is c onfirmed.