TEMPERATURE BROADENING OF IMPURITY TRANSITIONS IN THE CRYSTALLINE ANDGLASSY PHASE OF BENZOPHENONE

Citation
J. Kikas et al., TEMPERATURE BROADENING OF IMPURITY TRANSITIONS IN THE CRYSTALLINE ANDGLASSY PHASE OF BENZOPHENONE, Chemical physics letters, 207(2-3), 1993, pp. 143-147
Citations number
34
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
ISSN journal
00092614
Volume
207
Issue
2-3
Year of publication
1993
Pages
143 - 147
Database
ISI
SICI code
0009-2614(1993)207:2-3<143:TBOITI>2.0.ZU;2-T
Abstract
The temperature dependence of the width of spectral holes in the cryst alline and glassy phase of benzophenone: chlorin solid solutions is me asured between 1.5 and 10 K. In the crystal, the holewidth levels on G AMMA(0) = 45 MHz for T < 5 K. This is close to the lifetime-limited va lue. For T > 5 K, it exhibits a rapid increase. In the glassy phase, t he holewidth exceeds that in the crystalline state by more than a fact or of ten. For T < 4 K, the width is governed by a power law with an e xponent of 1.28. Around 5 K, there is a clear onset of a much steeper dependence.