THE QUASI-CLASSICAL APPROXIMATION IN DELOS-THORSON CLOSE-COUPLED EQUATIONS FOR INELASTIC-SCATTERING

Citation
Dv. Shalashilin et al., THE QUASI-CLASSICAL APPROXIMATION IN DELOS-THORSON CLOSE-COUPLED EQUATIONS FOR INELASTIC-SCATTERING, Chemical physics letters, 207(2-3), 1993, pp. 250-256
Citations number
21
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
ISSN journal
00092614
Volume
207
Issue
2-3
Year of publication
1993
Pages
250 - 256
Database
ISI
SICI code
0009-2614(1993)207:2-3<250:TQAIDC>2.0.ZU;2-V
Abstract
For the description of inelastic scattering a new form of the close-co upled equations of Delos and Thorson is considered. The equations prop osed involve wavefunctions of elastic scattering in the quasiclassical approximation of Wentzel, Kramers and Brillouin (WKB). Under quasicla ssical conditions the number of coupled equations for quantum amplitud es is reduced to the number of semiclassical equations. The quasiclass ical equations are tested on the two-state exponential model. High acc uracy is achieved if the wavefunctions used take into account the comp licated structure of the Stokes phenomena. The structure of the Stokes jump is obtained numerically and visualized.