Dv. Shalashilin et al., THE QUASI-CLASSICAL APPROXIMATION IN DELOS-THORSON CLOSE-COUPLED EQUATIONS FOR INELASTIC-SCATTERING, Chemical physics letters, 207(2-3), 1993, pp. 250-256
For the description of inelastic scattering a new form of the close-co
upled equations of Delos and Thorson is considered. The equations prop
osed involve wavefunctions of elastic scattering in the quasiclassical
approximation of Wentzel, Kramers and Brillouin (WKB). Under quasicla
ssical conditions the number of coupled equations for quantum amplitud
es is reduced to the number of semiclassical equations. The quasiclass
ical equations are tested on the two-state exponential model. High acc
uracy is achieved if the wavefunctions used take into account the comp
licated structure of the Stokes phenomena. The structure of the Stokes
jump is obtained numerically and visualized.