THE Roe flux difference splitting scheme is investigated for accuracy
in simulating hypersonic reacting flows. The extension of the Roe sche
me to include the finite rate chemical kinetic equations follows the a
pproach of Grossman and Cinnella. Formal second-order accuracy is obta
ined by employing the monotonic upstream schemes for conservation laws
(MUSCL) approach in conjunction with the minmod limiter to degenerate
the solution to first-order accuracy in the vicinity of strong shock
waves. The full Navier-Stokes equations are solved with finite rate ch
emistry for the flow past an axisymmetric blunt body at zero incidence
at several Mach numbers. The vibrational energy is assumed to be in t
hermodynamic equilibrium with the other internal energy modes. The air
mixture is assumed to consist of the five species O2, O, N2, N, and N
O. The surface heat transfer predicted by this scheme is validated for
flows with Mach numbers 15.3 and 16.34 when compared with classical t
heory and experimental results. Both catalytic and noncatalytic wall b
oundary conditions are used. The entropy correction parameter, necessa
ry to enforce the entropy condition in Roe's scheme, is found to be a
simple and effective means to control numerical error due to the degen
erated eigenvalue structure in the stagnation region, thus suppressing
the numerical bulge or ''carbuncle'' phenomenon.