Development of scramjet engines requires a better knowledge of the cou
pling between supersonic flow and combustion chemical kinetics. In thi
s paper we consider a stationary uniform, laminar supersonic flow of a
hydrogen-air mixture on a flat plate. Conditions of the flow at the o
uter edge of the boundary layer are chosen such that the chemical time
is ''infinitely'' large when compared to the transit time over the co
mputational domain. Ignition is triggered inside the boundary layer by
viscous dissipation effects and/or wall temperature. This problem is
solved numerically by a finite difference technique coupled with a che
mical kinetics special solver and using classical boundary-layer assum
ptions, with two different types of boundary conditions: 1) adiabatic
wall, and 2) constant temperature wall. Ignition of the reactive mixtu
re within the boundary layer is observed as soon as either the freestr
eam Mach number or the wall temperature are large enough. The combusti
on zone can be described as made up of three different regions, each o
f which depending on a particular coupling between chemical kinetics a
nd fluid dynamics. The structure of this combustion zone is calculated
for various freestream Mach numbers, different chemical kinetic mecha
nisms, reactive mixture equivalence ratios, and freestream and wall te
mperatures.