THERMODYNAMIC ORIGIN OF PROLYL PEPTIDE-BOND ISOMERS

Authors
EBERHARDT ES LOH SN RAINES RT
Citation
Es. Eberhardt et al., THERMODYNAMIC ORIGIN OF PROLYL PEPTIDE-BOND ISOMERS, Tetrahedron letters, 34(19), 1993, pp. 3055-3056
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
34
Issue
19
Year of publication
1993
Pages
3055 - 3056
Database
ISI
SICI code
0040-4039(1993)34:19<3055:TOOPPI>2.0.ZU;2-4
Abstract
The preference for the trans isomer of prolyl peptide bonds arises alm ost entirely from enthalpy in aqueous buffer and in toluene.