REACTIONS OF (1-CHLOROVINYL)DIPHENYLPHOSPHINE OXIDE WITH ORGANOMETALLIC REAGENTS

Authors
CARDELLICCHIO C FIANDANESE V NASO F PIETRUSIEWICZ KM WISNIEWSKI W
Citation
C. Cardellicchio et al., REACTIONS OF (1-CHLOROVINYL)DIPHENYLPHOSPHINE OXIDE WITH ORGANOMETALLIC REAGENTS, Tetrahedron letters, 34(19), 1993, pp. 3135-3138
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
34
Issue
19
Year of publication
1993
Pages
3135 - 3138
Database
ISI
SICI code
0040-4039(1993)34:19<3135:RO(OWO>2.0.ZU;2-E
Abstract
Direct substitution of 1-chlorovinyl group by an aryl or an alkyl grou p in the reactions of (1-chlorovinyl)diphenylphosphine oxide with aryl and alkyl Grignard reagents was observed, whereas in its reactions wi th the corresponding cuprates addition across the double bond constitu ted the dominant reaction pathway.