THE BETA-NITROXYALKYL AND BETA-SULFONATOXYALKYL RADICAL REARRANGEMENTS

Authors
CRICH D FILZEN GF
Citation
D. Crich et Gf. Filzen, THE BETA-NITROXYALKYL AND BETA-SULFONATOXYALKYL RADICAL REARRANGEMENTS, Tetrahedron letters, 34(20), 1993, pp. 3225-3226
Citations number
9
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
34
Issue
20
Year of publication
1993
Pages
3225 - 3226
Database
ISI
SICI code
0040-4039(1993)34:20<3225:TBABRR>2.0.ZU;2-T
Abstract
The first examples of the migration of nitrate and sulfonate esters in beta-nitroxyalkyl and beta-sulfonatoalkyl radicals are presented: cro ssover and labelling experiments are used to determine the migrating g roup and the intramolecular nature of the rearrangement.