NUCLEOPHILIC AROMATIC-SUBSTITUTION ON AROMATIC ALDIMINES-PSI

Citation
La. Flippin et al., NUCLEOPHILIC AROMATIC-SUBSTITUTION ON AROMATIC ALDIMINES-PSI, Tetrahedron letters, 34(20), 1993, pp. 3255-3258
Citations number
9
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404039
Volume
34
Issue
20
Year of publication
1993
Pages
3255 - 3258
Database
ISI
SICI code
0040-4039(1993)34:20<3255:NAOAA>2.0.ZU;2-U
Abstract
Ortho-methoxy-substituted benzaldimines derived from 3-amino-2,4-dimet hylpentane undergo efficient nucleophilic aromatic substitution with t ypical organolithium reagents. The aldimine products can be hydrolyzed under mild conditions to provide ortho-alkyl or ortho-phenyl benzalde hyde derivatives.