SILYLCUPRATION OF N-PHENYL-N-ETHYNYL-ANILINE - A VERSATILE ROUTE TO FUNCTIONALIZED N,N-BIS(PHENYL)ENAMINES

Authors
CAPELLA L CAPPERUCCI A CUROTTO G LAZZARI D DEMBECH P REGINATO G RICCI A
Citation
L. Capella et al., SILYLCUPRATION OF N-PHENYL-N-ETHYNYL-ANILINE - A VERSATILE ROUTE TO FUNCTIONALIZED N,N-BIS(PHENYL)ENAMINES, Tetrahedron letters, 34(20), 1993, pp. 3311-3314
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
34
Issue
20
Year of publication
1993
Pages
3311 - 3314
Database
ISI
SICI code
0040-4039(1993)34:20<3311:SON-AV>2.0.ZU;2-P
Abstract
The silylcupration of N-phenyl-N-ethynyl-aniline, occurs regioselectiv ely leading to silylation at the beta-carbon atom. Subsequent reaction of the resulting vinyl copper adduct with electrophiles, opens a new flexible route to functionalized enamines.