EXPLANATION OF AN UNUSUAL SUBSTITUENT EFFECT IN THE BENZYLATION OF ANISOLE AND IDENTIFICATION OF THE ORIGIN OF THE ACTIVE-SITES IN CLAYZIC

Authors
BARLOW SJ BASTOCK TW CLARK JH CULLEN SR
Citation
Sj. Barlow et al., EXPLANATION OF AN UNUSUAL SUBSTITUENT EFFECT IN THE BENZYLATION OF ANISOLE AND IDENTIFICATION OF THE ORIGIN OF THE ACTIVE-SITES IN CLAYZIC, Tetrahedron letters, 34(20), 1993, pp. 3339-3342
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
34
Issue
20
Year of publication
1993
Pages
3339 - 3342
Database
ISI
SICI code
0040-4039(1993)34:20<3339:EOAUSE>2.0.ZU;2-F
Abstract
The surprisingly low reaction rate of anisole (compared to benzene) to wards ''Clayzic'' catalysed Friedel-Crafts benzylation at ambient temp erature, has been explained and used to show the presence and identify the origin of, both Bronsted and Lewis acid sites in ''Clayzic''.