N-SULFONYLBENZOTRIAZOLES .2. REACTIONS OF 1,1'-SULFONYLDIBENZOTRIAZOLE AND 1-BENZENESULFONYL-1,2,4-TRIAZOLE WITH ALCOHOLS - A NEW APPROACH TO N-ALKYLBENZOTRIAZOLES AND N-ALKYL-1,2,4-TRIAZOLES
Ar. Katritzky et al., N-SULFONYLBENZOTRIAZOLES .2. REACTIONS OF 1,1'-SULFONYLDIBENZOTRIAZOLE AND 1-BENZENESULFONYL-1,2,4-TRIAZOLE WITH ALCOHOLS - A NEW APPROACH TO N-ALKYLBENZOTRIAZOLES AND N-ALKYL-1,2,4-TRIAZOLES, Heterocycles, 36(6), 1993, pp. 1253-1262
1,1' Sulfonyldibenwtriazole (3) reacts with sodium alkoxides to give N
-alkylbenzotriazoles. With alkanols, benzotriazolium alkyl sulfates ar
e produced. 1-Benzenesulfonyl-1,2,4-triazole with the sodium salts of
alcohols gives 1-alkyl-1,2,4-triazoles. The mechanisms of these reacti
ons are discussed.