MATHEMATICAL-MODELING OF CHEMICAL CLOCK REACTIONS .2. A CLASS OF AUTOCATALYTIC CLOCK REACTION SCHEMES

Citation
J. Billingham et Dj. Needham, MATHEMATICAL-MODELING OF CHEMICAL CLOCK REACTIONS .2. A CLASS OF AUTOCATALYTIC CLOCK REACTION SCHEMES, Journal of engineering mathematics, 27(2), 1993, pp. 113-145
Citations number
18
Categorie Soggetti
Computer Application, Chemistry & Engineering",Mathematics,Engineering
ISSN journal
00220833
Volume
27
Issue
2
Year of publication
1993
Pages
113 - 145
Database
ISI
SICI code
0022-0833(1993)27:2<113:MOCCR.>2.0.ZU;2-P
Abstract
A clock reaction is a chemical reaction which gives rise to an initial induction period before a significant concentration of one of the che mical species involved is produced. We study four closely related isot hermal model reaction schemes which can exhibit clock reaction behavio ur in a well-stirred situation. These reaction schemes represent a com bination of quadratic or cubic autocatalysis with linear or quadratic inhibition.