REACTIVITY OF 4-AZIDO-6-METHYL-2H-PYRAN-2-ONE AND 4-AMINO-6-METHYL-2H-PYRAN-2-ONE - PREPARATION OF 1-(6-METHYL-2-OXOPYRAN-4-YL)-1,2,3-TRIAZOLES AND 5-OXOPYRANO[4,3-B]PYRIDINES

Authors
MALET R SERRA N ABRAMOVITCH RA MORENOMANAS M PLEIXATS R
Citation
R. Malet et al., REACTIVITY OF 4-AZIDO-6-METHYL-2H-PYRAN-2-ONE AND 4-AMINO-6-METHYL-2H-PYRAN-2-ONE - PREPARATION OF 1-(6-METHYL-2-OXOPYRAN-4-YL)-1,2,3-TRIAZOLES AND 5-OXOPYRANO[4,3-B]PYRIDINES, Journal of heterocyclic chemistry, 30(2), 1993, pp. 317-321
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of heterocyclic chemistry → ACNP
ISSN journal
0022152X
Volume
30
Issue
2
Year of publication
1993
Pages
317 - 321
Database
ISI
SICI code
0022-152X(1993)30:2<317:RO4A4>2.0.ZU;2-B
Abstract
1,3-Dipolar cycloadditions of stable 4-azido-6-methyl-2H-pyran-2-one 1 with electron-rich alkenes and alkynes lead to 4,5-substituted 146-me thyl-2-oxopyran-4-yl)-1,2,3-triazoles. Iminophosphoranes derived from 1 have also been synthesized. 5-Oxopyrano[4,3-b]pyridines are prepared by reaction of 4-amino-6-methyl-2H-pyran-2-one 2 with beta-dicarbonyl compounds.