PREPARATION AND REACTIVITY OF METAL-CONTAINING MONOMERS .21. SPONTANEOUS POLYMERIZATION OF ACRYLAMIDE COORDINATED TO METAL NITRATES

Authors
SAVOSTYANOV VS VASILETS VN ERMAKOV OV SOKOLOV EA POMOGAILO AD KRITSKAYA DA PONOMAREV AN
Citation
Vs. Savostyanov et al., PREPARATION AND REACTIVITY OF METAL-CONTAINING MONOMERS .21. SPONTANEOUS POLYMERIZATION OF ACRYLAMIDE COORDINATED TO METAL NITRATES, Bulletin of the Russian Academy of Sciences, Division of Chemical Sciences, 41(9), 1992, pp. 1615-1620
Citations number
13
Categorie Soggetti
Chemistry
Journal title
Bulletin of the Russian Academy of Sciences, Division of Chemical Sciences → ACNP
ISSN journal
10635211
Volume
41
Issue
9
Year of publication
1992
Part
1
Pages
1615 - 1620
Database
ISI
SICI code
1063-5211(1992)41:9<1615:PAROMM>2.0.ZU;2-N
Abstract
Acrylamide coordinated to Cr(III), Bi(III), Pb(II), and Ca(II) nitrate s polymerizes spontaneously in concentrated aqueous solutions at appro ximately 20-degrees-C with formation of glass-like polymers containing water. The process takes from several hours to several days, dependin g on reaction conditions and the nature of the metal nitrate. The prod uct contains water-soluble and water-insoluble fractions. The insolubl e fraction is polyacrylamide containing no metal compound. The possibi lity of spontaneous copolymerization of acrylamide complexes of metal nitrates with other water-soluble monomers was established.