Bn. Popov et al., GALVANOSTATIC PULSE AND PULSE REVERSE PLATING OF NICKEL-IRON ALLOYS FROM ELECTROLYTES CONTAINING ORGANIC-COMPOUNDS ON A ROTATING-DISK ELECTRODE, Journal of the Electrochemical Society, 140(5), 1993, pp. 1321-1330
Linear sweep voltammetry, galvanostatic pulse, and pulse reverse techn
iques were used to study the plating of nickel-iron alloys in the pres
ence of organic additives. The effects of pulse current densities, i(p
), reverse current densities, i(r), rotation speed of disk electrode,
and the presence of organic additives on deposition of nickel-iron all
oys are evaluated. The observed phenomena can be explained by the conc
entration depletion of reactants (or products), and the surface covera
ge of the additives on the electrode. A new formulation of the plating
bath is defined.