Jhpm. Emmen et al., GROWTH OF BI-(SR,LA)-CU-O SINGLE-CRYSTALS WITH THE FLOATING-ZONE TECHNIQUE, Journal of alloys and compounds, 195(1-2), 1993, pp. 15-18
The TSFZ method has been used to grow crystals of the Bi-oxide superco
nductor of the Bi-n = 1 structure. The investigated compositions are B
i2Sr2CuO6+z, Bi2.3Sr1.7CuO6+z, and Bi2+xSr1.6-LayCuO6+z (x+y = 0.4). E
xcept for the stoichiometric composition, the TSFZ experiments yield p
late-like crystals of the superconducting R-phase. Superconductivity w
as only present in La substituted crystals and the Tc could be changed
by annealing procedures. A maximum T(c) = 29 K is found for Bi2.0Sr1.
6La0.4CuO6+z.