Bi-containing ''2201'' and ''2212'' high temperature superconductor (H
TSC) coatings have been obtained on silver substrates and wires using
solution techniques. At different thermal conditions at least two stru
cture modifications of the ''2201'' precursor phase are formed. These
modifications have different morphology, chemical composition and crys
tal structure. Features of the transition between the phases mentioned
are discussed. Needle-like grains of the 2201 high temperature phase
are shown to be textured along the wire axis. HTSC coatings of 2212 co
mposition replicate the texture of the precursor phase 2201.