Sodium metaborate and metasilicate coatings protect pure iron in the t
emperature range 800 to 1,000-degrees-C. Metaborate and metasilicate i
nhibit oxidation. Protective vonsenite (4FeO x Fe2O3 x B2O3) forms wit
h metaborate, and protective fayalite (2FeO x SiO2) forms with metasil
icate. It is proposed that noncoherent blocking layers of these compou
nds effectively decrease the interface area for iron ion diffusion.