Growth modes and electronic properties of ultra-thin films of copper d
eposited on the V(100) surface were studied over a wide temperature ra
nge (220-1200 K). XPS, LEED, TDS and angular resolved UPS data are pre
sented. At 300 K, initially, two copper layers grow in an ordered, ''l
ayer-by-layer'' mode, in registry with the V(100) surface. These layer
s are stable over the whole of the studied temperature range (300 K --
> desorption onset). Further copper deposition results in a disordered
him growth where more layers grow at the same time, probably with dif
ferent structures. In the temperature range 300-600 K, an increased mo
bility of Cu atoms induces, gradually, the formation of 3D clusters on
a supporting copper layer. (C) 1997 Elsevier Science B.V.