REACTION BETWEEN METHYL(METH)ACRYLATE AND N,N-DIMETHYLAMINOPROPYLAMINE

Authors
SHIRSHIN KV KAZANTSEV OA ZILBERMAN EN DANOV SM SALOV VN
Citation
Kv. Shirshin et al., REACTION BETWEEN METHYL(METH)ACRYLATE AND N,N-DIMETHYLAMINOPROPYLAMINE, Journal of applied chemistry of the USSR, 65(6), 1992, pp. 1148-1152
Citations number
10
Categorie Soggetti
Chemistry Applied
Journal title
Journal of applied chemistry of the USSR → ACNP
ISSN journal
0021888X
Volume
65
Issue
6
Year of publication
1992
Part
2
Pages
1148 - 1152
Database
ISI
SICI code
0021-888X(1992)65:6<1148:RBMAN>2.0.ZU;2-Z
Abstract
A study was made of the reaction between methyl(meth)acrylate and N,N- dimethylaminopropylamine at 20-240-degrees-C to establish the effect t hat reagent ratio and structure, temperature, and catalyst type have o n the competing reactions in the system. Addition of amino groups at t he C=C bonds and amidation of the ester groups were found to be the pr incipal. interactions. It was shown that addition reactions predominat ed at lower temperatures (up to 125-degrees-150-degrees-C). Lead(II) a cetate was observed to accelerate amidation just as effectively as kno wn organotin catalysts.