NUCLEAR-QUADRUPOLE HYPERFINE-STRUCTURE AND METHYL TORSIONAL FINE-STRUCTURE IN THE ROTATIONAL SPECTRA OF N,N-DIMETHYLFORMAMIDE AND N-NITROSODIMETHYLAMINE

Authors
HEINEKING N DREIZLER H
Citation
N. Heineking et H. Dreizler, NUCLEAR-QUADRUPOLE HYPERFINE-STRUCTURE AND METHYL TORSIONAL FINE-STRUCTURE IN THE ROTATIONAL SPECTRA OF N,N-DIMETHYLFORMAMIDE AND N-NITROSODIMETHYLAMINE, Zeitschrift fur Naturforschung. A, A journal of physical sciences, 48(4), 1993, pp. 570-576
Citations number
15
Categorie Soggetti
Chemistry Physical",Physics
Journal title
Zeitschrift fur Naturforschung. A, A journal of physical sciences → ACNP
ISSN journal
09320784
Volume
48
Issue
4
Year of publication
1993
Pages
570 - 576
Database
ISI
SICI code
0932-0784(1993)48:4<570:NHAMTF>2.0.ZU;2-7
Abstract
The complicated nuclear quadrupole hyperfine structure and methyl tors ional fine structure in the rotational spectra of N,N-dimethylformamid e and N-nitrosodimethylamine have been studied using microwave Fourier transform spectroscopy. It has been found that both molecules are rat her similar in terms of their parameters of methyl group internal rota tion as well as in terms of their amino nitrogen quadrupole coupling c onstants.