SURFACE DIPOLE-MOMENTS FROM LEED INVESTIGATIONS

Citation
V. Fritzsche et al., SURFACE DIPOLE-MOMENTS FROM LEED INVESTIGATIONS, Surface science, 289(3), 1993, pp. 389-396
Citations number
37
Categorie Soggetti
Chemistry Physical
Journal title
ISSN journal
00396028
Volume
289
Issue
3
Year of publication
1993
Pages
389 - 396
Database
ISI
SICI code
0039-6028(1993)289:3<389:SDFLI>2.0.ZU;2-A
Abstract
Alkali adsorbates on transition metals have traditionally given Poor R factors for LEED theory/ experiment comparison. In this paper we post ulate that at least part of the remaining discrepancy is due to the no n-spherical potential caused by a dipole moment on the alkali atom. In clusion of a dipole in the fitting procedure gives a reasonable magnit ude for the dipole, and a location not far from the centre of the alka li. The R factor shows a substantial improvement.