N. Koguchi et K. Ishige, GROWTH OF GAAS EPITAXIAL MICROCRYSTALS ON AN S-TERMINATED GAAS SUBSTRATE BY SUCCESSIVE IRRADIATION OF GA AND AS MOLECULAR-BEAMS, JPN J A P 1, 32(5A), 1993, pp. 2052-2058
Numerous GaAs epitaxial microcrystals with an average base size of 250
angstrom x 430 angstrom with (111) facets were fabricated on a sulfur
-terminated (S-terminated) GaAs (001) substrate with successive irradi
ation of Ga and As molecular beams. The growth of GaAs microcrystals o
n the S-terminated substrate was caused by a vapor-liquid-solid (VLS)
mechanism. This phenomenon originated in the inertness for the adhesio
n of Ga and As molecules and nearly equal lattice constants of the S-t
erminated GaAs surface and GaAs surface. This method, called droplet e
pitaxy, is thought to show promise as a growth method for fabricating
GaAs quantum well boxes.