Ionized cluster beam (ICB) deposition has been used to form thin films
of metals, insulators, semiconductors and organic materials which hav
e unique characteristics when compared to films formed using other tec
hniques. In addition, the use of gas-phase atoms in the form of accele
rated clusters has recently shown promise for surface modification app
lications. A fundamental understanding of ICB deposition and related t
echniques requires investigations of (1) the mechanisms which lead to
the growth of large vapor phase clusters, (2) techniques for determini
ng the size distribution of large vapor clusters, (3) the initial stag
es of film nucleation, (4) film growth morphology related to lattice m
ismatch and ion beam parameters. Clarification of the role of clusters
in ICB deposition has been greatly aided by atomic scale imaging by t
ransmission electron microscopy and scanning tunnel microscopy in the
early stages of film growth. Emphasis is given to the formation of hig
h-quality, epitaxial metallic films. Several applications of ICB films
with respect to microelectronics, optical mirrors, compound materials
and organic materials are discussed with emphasis on the special char
acteristics of ICB films. Applications for gas-cluster processing are
reviewed.