SYNTHESIS AND CHARACTERIZATION OF OLIGOMERIC MOLYBDENUM COMPLEXES OF N-ALKYLPHENOTHIAZINES

Authors
GOWDA NMM ACKERSON BE MORLAND M RANGAPPA KS
Citation
Nmm. Gowda et al., SYNTHESIS AND CHARACTERIZATION OF OLIGOMERIC MOLYBDENUM COMPLEXES OF N-ALKYLPHENOTHIAZINES, Transition metal chemistry, 18(3), 1993, pp. 271-274
Citations number
24
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Transition metal chemistry
ISSN journal
03404285 → ACNP
Volume
18
Issue
3
Year of publication
1993
Pages
271 - 274
Database
ISI
SICI code
0340-4285(1993)18:3<271:SACOOM>2.0.ZU;2-Q
Abstract
Polynuclear molybdenum(IV/V) oxide - phenothiazine complexes which are oligomeric in nature have been prepared. The complexes were character ized by elemental analyses and spectroscopic data. The molecular formu lae of the new complexes are [Mo4O9(OH2)2(PTZ)2], PTZ = chlorpromazine or promethazine, [Mo4O8(OH2)2(TR)2], TR=thioridazine, [Mo5O10(OH2)2(E P)2], EP=ethopropazine, and [Mo6O12(OH2)2(TF)2], TF = trifluoperazine. Tentative structures are proposed.