M. Antosik et S. Malanowski, LIQUID - LIQUID EQUILIBRIA IN HYDROCARBON PLUS 3-METHOXYPROPIONITRILESYSTEMS, CORRELATION AND PREDICTION, Fluid phase equilibria, 85, 1993, pp. 161-170
Liquid-liquid equilibria (LLE) for ternary system n-hexadecane + butyl
benzene + 3-methoxypropionitrile (3MOPN) at 298.15 K are reported. The
se experimental results and earlier published ones dealing with mixtur
es of other hydrocarbons and 3MOPN were correlated using the NRTL and
the UNIQUAC equations. The UNIFAC-LLE parameters for the some hydrocar
bons groups with 3MOPN were calculated from experimental binary and te
rnary LLE. The prediction of liquid-liquid equilibria for ternary hydr
ocarbons + 3MOPN systems were compared with the experimental data.