EFFECTS OF MONOMER FEED METHODS IN EMULSION POLYMERIZATIONS AND HYDROPHILICITY OF MONOMERS ON MORPHOLOGY OF LATEX-PARTICLES AND THEIR MINIMUM FILM FORMATION TEMPERATURES
Ty. Cao et al., EFFECTS OF MONOMER FEED METHODS IN EMULSION POLYMERIZATIONS AND HYDROPHILICITY OF MONOMERS ON MORPHOLOGY OF LATEX-PARTICLES AND THEIR MINIMUM FILM FORMATION TEMPERATURES, Polymer international, 32(2), 1993, pp. 153-158
The paper describes the synthesis of polymer emulsions of methylmethac
rylate-methylacrylate, methylmethacrylate-ethylacrylate, and methylmet
hacrylate-2-ethylhexylacrylate systems by different monomer feed metho
ds. The minimum film formation temperatures of the emulsions were dete
rmined. The morphology of the latex particles was observed by electron
microscopy. It was found that the effects of monomer feed methods and
the hydrophilicity of the monomers on both the morphology of the late
x particles and the minimum film formation temperatures of their emuls
ions are significant.