N-23 AND C-13 SOLID-STATE NMR-SPECTROSCOPY OF TETRAMETHYLETHYLENEDIAMINE-SODIUMCYCLOPENTADIENIDE

Authors
PIETRASS T BURKERT PK
Citation
T. Pietrass et Pk. Burkert, N-23 AND C-13 SOLID-STATE NMR-SPECTROSCOPY OF TETRAMETHYLETHYLENEDIAMINE-SODIUMCYCLOPENTADIENIDE, Inorganica Chimica Acta, 207(2), 1993, pp. 253-254
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganica Chimica Acta → ACNP
ISSN journal
00201693
Volume
207
Issue
2
Year of publication
1993
Pages
253 - 254
Database
ISI
SICI code
0020-1693(1993)207:2<253:NACSNO>2.0.ZU;2-3
Abstract
The static Na-23 NMR spectrum of tetramethylethylenediamine-sodiumcycl opentadienide revealed a lineshape that could not be unambiguously dis cussed. Nutation NMR spectroscopy combined with MAS allowed a definite assignment of the splitted signal to a second order quadrupolar inter action with vanishing asymmetry parameter. The quadrupole coupling con stant is in the range of 2 MHz. The C-13 CP-MAS spectrum yielded the e xpected signals.