M. Mitov et P. Sixou, STUDY OF A CHOLESTERIC LIQUID-CRYSTAL POLYMER IN SOLUTION IN A LOW MOLAR WEIGHT LIQUID-CRYSTAL - PHASE-DIAGRAM AND ELECTRIC-FIELD EFFECT, Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals, 231, 1993, pp. 11-28
We have studied the effect of an electric field on a binary mixture be
tween a cholesteric liquid crystal polymer and a low molar weight liqu
id crystal from results a cholesteric polymer film in a confined geome
try. The phase diagram shows, moreover an excellent compatibility betw
een the compounds, a very large variation of the cholesteric pitch. Ac
cording to the magnitude and the frequency of the applied electric fie
ld, various behaviours are observed: stable homeotropic nematic, stabl
e birefringent filaments, ''fingerprint'' texture, . . . We have focus
ed our study on the effect of an electric field on the filament textur
e corresponding to a large cholesteric pitch. The transition of a text
ure with filaments to a homeotropic structure is described by the exis
tence of two optical thresholds (the appearance of the homeotropic and
the disappearance of the filaments) whom the variation is studied acc
ording to the frequency. We are describing particular phenomena added
to this general behaviour, like the nucleation and the growth under fi
eld of quasi perfect spirals issue of the bending of the filaments jus
t before the obtaining of the homeotropic state. Besides, we give an e
xample where the quenching of the spiral texture is possible thanks to
the polymeric compound of the binary mixture. From the configuration
of the filament proposed by Lequeux or Oswald et al., it is possible t
o imagine a mechanism where, in given conditions, a propagation of the
authors' structure is produced.