Rt. Bailey et al., THE LINEAR OPTICAL-PROPERTIES OF THE ORGANIC MOLECULAR-CRYSTAL (-(ALPHA-METHYLBENZYL-AMINO)-5-NITROPYRIDINE (MBA-NP)()2), Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals, 231, 1993, pp. 223-229
The linear optical properties of the organic molecular crystal (+)2-(a
lpha-methylbenzylamino)-5-nitropyridine (MBA-NP) are investigated. The
specific rotation associated with this chiral molecule has been deter
mined as +239.11-degrees. The effective transparency range for nonline
ar optical applications was found to be 465-1500 nm, with a 10 nm dich
roism in the high frequency absorption edge position. MBA-NP displays
angular dispersion to a larger extent than any other known organic non
linear material, a 200 nm change in the wavelength of the incident lig
ht causing a 40-degrees rotation of the dielectric axes. The linear re
fractive indices of MBA-NP have been determined using the minimum devi
ation technique, Maker fringe spacings and phase-matching directions.
The principal refractive index dispersion curves are fitted with a Sel
lmeier equation and the coefficients of this equation are presented fo
r the first time.