SYNTHESIS AND CRYSTAL AND MOLECULAR-STRUCTURE OF TETRAFLUORO[2-(PYRROLIDINIO)ETHYL]SILICATE

Authors
TACKE R LOPEZMRAS A BECHT J SHELDRICK WS
Citation
R. Tacke et al., SYNTHESIS AND CRYSTAL AND MOLECULAR-STRUCTURE OF TETRAFLUORO[2-(PYRROLIDINIO)ETHYL]SILICATE, Zeitschrift fur anorganische und allgemeine Chemie, 619(6), 1993, pp. 1012-1016
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
619
Issue
6
Year of publication
1993
Pages
1012 - 1016
Database
ISI
SICI code
0044-2313(1993)619:6<1012:SACAMO>2.0.ZU;2-E
Abstract
The zwitterionic tetrafluoro[2-(pyrrolidinio)ethyl]silicate (4) was sy nthesized by reaction of trimethoxy(2-pyrrolidinoethyl)silane (5) with hydrogen fluoride in ethanol/hydrofluoric acid at 0-degrees-C. The cr ystal and molecular structure of 4 was studied at - 100-degrees-C by s ingle-crystal X-ray diffraction. In addition, 4 was characterized by s olution-state NMR studies (CD3CN: H-1, C-13).