We have discovered that ionization without accompanying electron captu
re is an important process in slow (v is similar to 0.1-0.2 a.u.) Xe(q
+)-Xe collisions at very high projectile charge (q >25). The measured
absolute cross sections, although between one and two orders of magnit
ude lower than the ones for single-electron capture, increase rapidly
with q when q >25 and reach a level of approximately 1 x 10(-15) cm2 f
or q >30. We argue that the reaction mechanism for ionization of the h
eavier rare gases involves the formation of core-excited, autoionizing
, neutral target states.